Deposition methods

Deposition methods - surround (titrimetric methods of quantitative analysis, based on the use of chemical precipitation reactions, i.e. such chemical processes in solution in which one of produced substances precipitate.
Example of the method of deposition can be argentometry, which is based on reactions of education insoluble salts of silver. Methods of argentometry possible determination of chlorides, bromides, iodides, compounds of silver and other deposition Methods used in health, pharmaceutical and clinical laboratories.
Cm. also Titration.

Deposition methods - volumetric methods of quantitative analysis, based on precipitation reactions. Deposition methods are used in biochemical, sanitary and clinical laboratories in the analysis of water, blood, urine, and other
The essence of deposition methods is to define direct or reverse titration (see) volume of the investigated V and working V0 solutions containing an equivalent amount of the reacting substances. According to the titration and normality N0 working solution expect normality N, or the titer T researched solution:

where e is equivalent to the weight of the analyte. On these values, you can calculate the weight, the quantity of matter in a given volume of solution and its percentage in solution or test sample.
Widespread deposition methods are based on reactions of education insoluble salts of silver (argentometry). These include the method Mora, based on the reaction of interaction of ions of silver ions halogen:
Ag+ + Cl- = AgCl Games Like It.
Working solutions in this method are: solution of potassium chloride KCl (or NaCl), which is the exact hanging from chemically pure preparation, and the solution of silver nitrate AgNO3, the exact amount of which is set by Kcl. The indicator is the solution chronolocical potassium Csgo4, forming with silver ions red-brown precipitate chronolocical silver:
2Ag++CrO2-4 = Ag2CrO4 p
The appearance of painted sediment Ag2CrO4, falling after the deposition of silver halide, testifies to the end of titration.
Method Mora determine chlorides, bromides, iodides and silver compounds. Method is not applicable in alkaline and acid environment, in the presence of ammonia, solvent silver compounds and ions VA2+, Pb2+ precipitating and other ions indicators.
More often use the method of Folgarida, based on the reaction of interaction of ions of silver ions thiocyanate:
Ag++SCN- = AgSCN games like it.
Working solutions in this case are the solution AgNO3 and the solution Rodenstock potassium KSCN (or ammonium NH4SCN), the exact amount of which is established as a solution AgNO3. The indicator in the method is the solution gentoomaniac alum NH4Fe(SO4)2 · N2O in nitric acid.
Ions SCN - form with ions of Fe3+ complex ions red. The titration is complete, when the solution over the sediment becomes red, does not disappear when mixing. Method Folgard determine silver compounds, Rodney and reverse) chlorides, bromides and iodides. In this case the solution of salt halogen add solution AgNO3 obviously in excess nevoshedshy in response number AgNO3 titrated solution KSCN. Normality researched solution is:
where N', V', N", V" - normality and the amount of working solutions AgNO3 and KSCN, respectively, V - volume of the investigated solution. Method of Folgarida not applicable in the presence of oxidising substances that Deplete ions SCN-, and salts of mercury, precipitating these ions.
To the methods of deposition method is marcormedia based on reactions of education insoluble salts of mercury. Working solution in the method is the solution of nitric oxide mercury (Hg2(NO3)2. This method determines the halides forming ions Hg2+ precipitation Hg2Cl2, Hg2Br2, Hg2J2.
The indicator is a solution of iron thiocyanate (titrated to the disappearance of the red color solution) or diphenyl-Cabazon (forms abundant ions Hg; +
sediment blue) and other indicators.